Document Type: Original Research Article

Authors

1 Department of Chemistry, Lorestan University, Khoramabad 68151-44316, Iran

2 Institute of Physics of the Czech Academy of Sciences, Na Slovance 2, 18221 Prague 8, Czech Republic

Abstract

In this work, pyridine 4-carbaldehye semicarbazone Schiff base ligand (HL) was synthesized with condention of pyridine 4-carbaldehyde and semicarbazide hydrochloride in reflux method. The HL was characterized using the CHN elemental analysis, FT-IR, UV-Vis, and 1H NMR spectroscopy. The single crystals of HL prepared and used for the X-ray crystallography. Single-crystal X-ray diffraction revealed that, HL crystallized in a triclinic system with the space group P-1. The FT-IR spectra and X-ray crystallography results suggested that the HL ligand is in keto form.

Graphical Abstract

Keywords

[1] A.L. Berhanu, I. Mohiuddin, A.K. Malik, J.S. Aulakh, V. Kumar, K.H. Kim, Trend. Analyt. Chem., 2019, 116, 74–91.

[2] B. Bansod, T. Kumar, R. Thakur, S. Rana, I. Singh, Biosens. Bioelectron., 2017, 94, 443–455.

[3] X. Liu, J.R. Hamon, Coord. Chem. Rev., 2019, 389, 94–118.

[4] B. Shaabani, A.A. Khandar, F. Mahmoudi, S.S. Balula, L. Cunha-Silva, J. Mol. Struct., 2013, 1045, 55–61.

[5] B. Shaabani, A.A. Khandar, M. Dusek, M. Pojarova, F. Mahmoudi, Inorg. Chim. Acta, 2013, 394, 563–568.

[6] Y. Echegoyen, I. Suelves, M.J. Lazaro, M.L. Sanjuan, R. Moliner, Appl. Cat. A, 2007, 333, 229–237.

[7] S. Nayak, P. Gamez, B. Kozlevcar, A. Pevec, O. Roubeau, S. Dehnen, J. Reedijk, Polyhedron, 2010, 29, 2291–2296.

[8] S. Uddin, S. Hossain , A. Latif , R. karim, R.K. Mohapatra, K.E. Zahan, Am. J. Heterocycl. Chem., 2019, 5, 27–36.

[9] R.M. Mannar, A. Shalu, B. Cerstin, E. Martin, R. Dieter, Dalton Trans., 2005, 537–544.

[10] C. An, X. Feng, N. Zhao, P. Liu, T. Wang, Z. Lian, J. Coord. Chem., 2014, 67, 3621–3632.

[11] S. Banerjee, M. Nandy, S. Sen, S. Mandal, G.M. Rosair, A.M.Z. Slawin, C.J. Gómez-García, J.M. Clemente-Juan, E. Zangrando, N. Guidolin, S. Mitra, Dalton Trans., 2011, 40, 1652–1661.

[12] S. Chandra, S. Raizada, R. Verma, J. Chem. Pharm. Res., 2012, 4, 1612–1618.

[13] K. Dhahagani, M.P. Kesavan, G.G. VinothKumar, L. Ravi, G. Rajagopal, J. Rajesh, Mater. Sci. Eng. C, 2018, 90, 119–130.

[14] M. Asadi, S. Torabi, K. Mohammadi, Spectrochim. Acta Part A., 2014, 122, 676–681.

[15] J. Ortega-Castro, M. Adrover, J. Frau, A. Salva, J. Donoso, F. Munoz, J. Phys. Chem. A, 2010, 114, 4634–4640.

[16] A. Ray, S. Banerjee, R.J. Butcher, C. Desplanches, S. Mitra, Polyhedron, 2008, 27, 2409–2415.

[17] S. Farhadi, M.M. Amini, M. Dusek, M. Kucerakova, F. Mahmoudi, J. Mol. Struct., 2017, 1130, 592–602.

[18] S. Farhadi, F. Mahmoudi, M. Dusek, V. Eigner, M. Kucerakova, Polyhedron, 2017, 122, 247–256.

[19] D. Kovala-Demertzi, P. Nath Yadav, J. Wiecek, S. Skoulika, T. Varadinova, M.A. Demertzis, J. Inorg. Biochem., 2006, 100, 1558–1567.

[20] R.J. Kunnath, M. Sithambaresan, A. Ambili Aravindakshan, A. Natarajan, M.R. Prathapachandra Kurup, polyhedron, 2016, 113, 73–80.

[21] P. Anitha, N. Chitrapriya, Y.J. Jang, P. Viswanathamurthi, J. Photochem. Photobiol. A, 2013, 129, 17–26.

[22] N.C. Kasuga, K. Onodera, S. Nakano, K. Hayashi, K. Nomiya, J. Inorg. Biochem., 2006, 100, 1176–1186.

[23] J. Benitez, L. Becco, I. Correia, S. Milena Leal, H. Guiset, J. Costa Pessoa, J. Lorenzo, S. Tanco, P. Escobar, V. Moreno, B. Garat, D. Gambino, J. Inorg. Biochem., 2011, 105, 303-312.

[24] H. Elo, Z. Naturforsch. C., 2007, 62, 498–506.

[25] B. Shaabani, A.A. Khandar, F. Mahmoudi, M.A. Maestro, S.S. Balula, L.C. Silva, Polyhedron, 2013, 57, 118–126.

[26] S. Sugasawa, K. Mizukami, Pharm. Bull., 1955, 3, 393–393.

[27] E.G. Novikov, A.G. Pozdeeva, L.D. Stonov, L.A. Bakumenko, Khim. Selsk. Khoz., 1966, 4, 435–437.

[28] B. Shaabani, A.A. Khandar, M. Dusek, M. Pojarova, F. Mahmoudi, A. Feher, M. Kajňaková, J. Coord. Chem., 2013, 66, 748–762.

[29] B. Shaabani, A.A. Khandar, M. Dusek, M. Pojarova, M.A. Maestro, R. Mukherjee, F. Mahmoudi, J. Coord. Chem., 2014, 67, 2096–2109.

[30] S. Farhadi, F. Mahmoudi, J. Simpson, J.  Mol. Struct., 2016, 1108, 583–589.

[31] Oxford Diffraction LTd. CrysAlis CCD; Oxford Diffraction: Abington, England, 2006.

[32]  L. Palatinus, G. Chapuis, J. Appl. Cryst., 2007, 40, 786–790.