CiteScore: 5.0     h-index: 22

Document Type : Original Research Article

Authors

1 Faculty of Pharmacy, Department of Pharmaceutics, University of Al-Ameed, Iraq

2 Al-Farahidi University, College of Medical Technology, Medical Lab. Techniques Department, Baghdad, Iraq

3 Department of Medical Engineering Al-Manara College for Medical Sciences, Maysan, Iraq

4 College of Pharmacy, National University of Science and Technology, Dhi Qar, Iraq

5 Department of Medical Engineering, Al-Hadi University College, Baghdad, Iraq

6 Department of Pharmacy, Al-Zahrawi University College, Karbala, Iraq

7 Department of Medical Engineering, Mazaya University College, Iraq

8 Department of Medical Laboratories Technology, AL-Nisour University College, Baghdad, Iraq

10.48309/ajca.2024.449003.1501

Abstract

The hydrothermal synthesis of ZnO/CdS nanocomposite studied for photocatalytic degradation of Amoxicillin (AMX) drug. The physical and chemical properties of the prepared ZnO/CdS were characterized using several analyses such as TEM, FE-SEM, TGA, and EDX. The photodegradation of Amoxicillin (AMX) drug was studied by employing UV-Vis light under several conditions in the presence of ZnO-CdS nanocomposite. Influence of several parameters such as AMX concentration (10-80 mg/L), mass of nanocomposite (0.1-0.4 g), and regeneration of ZnO-CdS nanocomposite was studied and optimized. All experiments were carried out under the most optimum conditions, which included a drug concentration of 30 mg/L, a light intensity of 1.2 mW/cm2, and a solution pH of 6.8. The results showed that the photocatalytic efficiency rose with reducing concentration of AMX (95.99%-53.12%) when concentration increased from 10 to 80 mg/L. The photocatalytic degradation increased when the weight of the ZnO-CdS nanocomposite increased (44.43%-98.99%). It was observed that the photocatalytic efficiency of AMX was 80.86%-72.77.85% for the first to fourth cycles. This indicates the best stability of nanocomposites and could be potentially useful in practical batch degradation.

Graphical Abstract

Photocatalytic Degradation of Amoxicillin Drug using ZnO/CdS Nanocomposite for Aqueous Solutions by using AOPs

Keywords

Main Subjects

[1] R. Mohamed, E.S. Aazam, Preparation and characterization of platinum doped porous titania nanoparticles for photocatalytic oxidation of carbon monoxide, Journal of alloys and compounds, 2011, 509, 10132-10138. [Crossref], [Google Scholar], [Publisher]
[2] A. Aljeboree, S. Essa, Z. Kadam, F. Dawood, D. Falah, A. AF, Environmentally friendly activated carbon derived from palm leaf for the removal of toxic reactive green dye, International Journal of Pharmaceutical Quality Assurance, 2023, 14, 12-15. [Google Scholar]
[3] S.S. Sambaza, A. Maity, K. Pillay, Polyaniline-coated TiO2 nanorods for photocatalytic degradation of bisphenol A in water, ACS omega, 2020, 5, 29642-29656. [Crossref], [Google Scholar], [Publisher]
[4] K.M. Reza, A. Kurny, F. Gulshan, Parameters affecting the photocatalytic degradation of dyes using TiO 2: a review, Applied Water Science, 2017, 7, 1569-1578. [Crossref], [Google Scholar], [Publisher]
[5] S.L. Wong, M.H. Mohamed Noor, N. Ngadi, I. Mohammed Inuwa, R. Mat, N.A. Saidina Amin, Aspirin adsorption onto activated carbon derived from spent tea leaves: statistical optimization and regeneration study, International Journal of Environmental Research, 2021, 15, 413-426. [Crossref], [Google Scholar], [Publisher]
[6] N. Abd Alrazzak, S.A. Aowda, A.J. Atiyah, Removal Bismarck Brown G dye from aqueous solution over a composite of triazole-polyvinyl chloride polymer and zinc oxide, Oriental Journal of Chemistry, 2017, 33, 2476-2483. [Crossref], [Google Scholar], [Publisher]
[7] S.T. Saad, H.Y. Al-Gubury, N. Alrazzak, Photocatalytic degradation of monoazo dye in ethanol using zinc oxide in ultra-violet radiation, Asian Journal of Chemistry, 2018, 30, 2334-2336. [Crossref], [Google Scholar], [Publisher]
[8] R. Syah, A. Hussein Altajer, O. F Abdul-Rasheed, F. Amri Tanjung, A. M Aljeboree, N. Abd Alrazzak, A. F Alkaim, CuMoO4/ZnO nanocomposites: novel synthesis, characterization, and photocatalytic performance, Journal of Nanostructures, 2021, 11, 73-80. [Crossref], [Google Scholar], [Publisher]
[9] V. Bakhshi, H. Poursadegh, M.S. Amini-Fazl, D. Salari, S. Javanbakht, Synthesis and characterization of bio-nanocomposite hydrogel beads based on magnetic hydroxyapatite and chitosan: a pH-sensitive drug delivery system for potential implantable anticancer platform, Polymer Bulletin, 2023, 1-20. [Crossref], [Google Scholar], [Publisher]
[10] P.V. Gayathri, D. Nair, G. Gopinath, D. Pilla, S. Joseph, Solar photocatalysis for the decontamination of water from emerging pharmaceutical pollutant chloroquine using Nano ZnO as the catalyst, Water, Air, & Soil Pollution, 2023, 234, 146. [Crossref], [Google Scholar], [Publisher]
[11] Y. Kamari, M. Ghiaci, Preparation and characterization of ibuprofen/modified chitosan/TiO2 hybrid composite as a controlled drug-delivery system, Microporous and Mesoporous Materials, 2016, 234, 361-369. [Crossref], [Google Scholar], [Publisher]
[12] A. Sharma, R. Nagraik, S. Sharma, G. Sharma, S. Pandey, S. Azizov, P.K. Chauhan, D. Kumar, Green synthesis of ZnO nanoparticles using Ficus palmata: Antioxidant, antibacterial and antidiabetic studies, Results in Chemistry, 2022, 4, 100509. [Crossref], [Google Scholar], [Publisher]
[13] M. Yilmaz, C. Cirak, N. Canpolat, S. Aydogan, ZnO micro/nanorods: their performance in the photocatalytic degradation and photodiode, Applied Physics A, 2023, 129, 224. [Crossref], [Google Scholar], [Publisher]
[14] K.P. Sundar, S. Kanmani, Progression of Photocatalytic reactors and it’s comparison: A Review, Chemical Engineering Research and Design, 2020, 154, 135-150. [Crossref], [Google Scholar], [Publisher]
[15] Z.D. Alhattab, A.M. Aljeboree, M.A. Jawad, F.S. Sheri, A.K. Obaid Aldulaim, A.F. Alkaim, Highly adsorption of alginate/bentonite impregnated TiO2 beads for wastewater treatment: Optimization, kinetics, and regeneration studies, Caspian Journal of Environmental Sciences, 2023, 21, 657-664. [Crossref], [Google Scholar], [Publisher]
[16] M. Mashkour, A. Al-Kaim, L. Ahmed, F. Hussein, Zinc oxide assisted photocatalytic decolorization of Reactive Red 2 dye, International Journal of Chemical Sciences, 2011, 9, 969-979. [Google Scholar], [Publisher]
[17] R. Nithya, S. Ragupathy, D. Sakthi, V. Arun, N. Kannadasan, Photocatalytic efficiency of brilliant green dye on ZnO loaded on cotton stalk activated carbon, Materials Research Express, 2020, 7, 075002. [Crossref], [Google Scholar], [Publisher]
[18] J.P. Dhal, B.G. Mishra, G. Hota, Hydrothermal synthesis and enhanced photocatalytic activity of ternary Fe 2 O 3/ZnFe 2 O 4/ZnO nanocomposite through cascade electron transfer, RSC Advances, 2015, 5, 58072-58083. [Crossref], [Google Scholar], [Publisher]
[19] S. Halder, R. Dammalapati, B. Bhaduri, ZnO nanoparticles dispersed in nitrogen-enriched carbon matrix for the efficient adsorption and photocatalytic degradation of aqueous methylene blue molecules, Inorganic Chemistry Communications, 2023, 158, 111685. [Crossref], [Google Scholar], [Publisher]
[20] R. Komala Dewi, H. H Kzar, W. Suksatan, I. Taukhid, H. Setia Budi, A. F Alkaim, S. Aravindhan, Synthesis and morphological investigation of hydroxyapatite/zinc oxide and evaluation its application in removal of organic pollutants, Journal of Nanostructures, 2021, 11, 368-376. [Crossref], [Google Scholar], [Publisher]
[21] I.A. Latif, H.M. Abdullah, S.H. Marza, A.H. Al-Dujaili, E.T. Bakir, Synthesis, Characterization and Electrical Properties of ZnO Nanoparticles Dispersed in Poly (vinyl acetal)/PVA Composite, Asian Journal of Chemistry, 2013, 25, 7753-7757. [Google Scholar]
[22] N. Matinise, X. Fuku, K. Kaviyarasu, N. Mayedwa, M. Maaza, ZnO nanoparticles via Moringa oleifera green synthesis: Physical properties & mechanism of formation, Applied Surface Science, 2017, 406, 339-347. [Crossref], [Google Scholar], [Publisher]
[23] X. Zhang, R. Zhang, A. Yang, Q. Wang, R. Kong, F. Qu, Aptamer based photoelectrochemical determination of tetracycline using a spindle-like ZnO-CdS@ Au nanocomposite, Microchimica Acta, 2017, 184, 4367-4374. [Crossref], [Google Scholar], [Publisher]
[24] H. Zhang, C. Yan, Q. Zhu, Theoretical investigation on the optical and EPR spectra for Cu2+‐doped ZnO‐CdS nanocomposites, Magnetic Resonance in Chemistry, 2019, 57, 144-148. [Crossref], [Google Scholar], [Publisher]
[25] G.T. Rao, B. Babu, R.J. Stella, V.P. Manjari, C.V. Reddy, J. Shim, R. Ravikumar, Synthesis and characterization of VO2+ doped ZnO–CdS composite nanopowder, Journal of Molecular Structure, 2015, 1081, 254-259. [Crossref], [Google Scholar], [Publisher]
[26] L. Li, H. Shi, H. Yu, X. Tan, Y. Wang, S. Ge, A. Wang, K. Cui, L. Zhang, J. Yu, Ultrathin MoSe2 nanosheet anchored CdS-ZnO functional paper chip as a highly efficient tandem Z-scheme heterojunction photoanode for scalable photoelectrochemical water splitting, Applied Catalysis B: Environmental, 2021, 292, 120184. [Crossref], [Google Scholar], [Publisher]
[27] S. Jalali, M. Ardjmand, B. Ramavandi, F. Nosratinia, Removal of amoxicillin from wastewater in the presence of H2O2 using modified zeolite Y-MgO catalyst: An optimization study, Chemosphere, 2021, 274, 129844. [Crossref], [Google Scholar], [Publisher]
[28] A.M. Aljeboree, Z.D. Alhattab, U.S. Altimari, A.K.O. Aldulaim, A.K. Mahdi, A.F. Alkaim, Enhanced removal of amoxicillin and chlorophenol as a model of wastewater pollutants using hydrogel nanocomposite: Optimization, thermodynamic, and isotherm studies, Caspian Journal of Environmental Sciences, 2023, 21, 411-422. [Crossref], [Google Scholar], [Publisher]
[29] M. Basit, M. Abbas, N. Ahmad, S. Javed, N.A. Shah, Synthesis of ZnO/CNT nanocomposites for ultraviolet sensors, Frontiers in Materials, 2022, 9, 835521. [Crossref], [Google Scholar], [Publisher]
[30] N.A. Hussain, A. Taifi, O.K.A. Alkadir, N.H. Obaid, Z.M. Abboud, A.M. Aljeboree, A.L. Al Bayaa, S.A. Abed, A.F. Alkaim, Role of Pomegranate peels as a activated carbon for removal of pollutants,  IOP conference series: earth and environmental science, IOP Publishing, 2022, 012028. [Crossref], [Google Scholar], [Publisher]
[31] F.H. Abdulrazzak, R.B. Jimaa, I.M. Radhi, T.A. Himdan, XRD and microscopic images for synthesis graphite nanoparticles by oxidation method, NeuroQuantology, 2021, 19, 45-49. [Crossref], [Google Scholar]
[32] R. Ali, I.M. Radhi, A.A. Ismail, F.H. Abdulrazzak, Modified ZnO for efficient photo-catalysis by silver/graphite oxide nanoparticles, Journal of Global Pharma Technology, 2009, 11, 143-150. [Google Scholar]
[33] Y. Kamari, P. Ghiaci, M. Ghiaci, Study on montmorillonite/insulin/TiO2 hybrid nanocomposite as a new oral drug-delivery system, Materials Science and Engineering: C, 2017, 75, 822-828. [Crossref], [Google Scholar], [Publisher]
[34] M. Pirsaheb, B. Shahmoradi, T. Khosravi, K. Karimi, Y. Zandsalimi, Solar degradation of malachite green using nickel-doped TiO2 nanocatalysts, Desalination and Water Treatment, 2016, 57, 9881-9888. [Crossref], [Google Scholar], [Publisher]
[35] K. Sivaranjani, S. Sivakumar, J. Dharmaraja, Enhancement photocatalytic activity of Mn doped CdS/ZnO nanocomposites for the degradation of methylene blue under solar light irradiation, Advances in Materials Science, 2022, 22, 28-48. [Crossref], [Google Scholar], [Publisher]
[36] A.S. Yusuff, B.A. Obende, T.C. Egbosiuba, Photocatalytic decolorization of textile effluent over ZnO nanoparticles immobilized on eucalyptus bark biochar: Parametric optimization, kinetic and economic analyses, Water Resources and Industry, 2024, 31, 100245. [Crossref], [Google Scholar], [Publisher]
[37] F.H. Abdulrazzak, F.H. Hussein, Photocatalytic hydrogen production on nanocomposite of carbon nanotubes and TiO2, Journal of Physics: Conference Series, IOP Publishing, 2018, 012056. [Crossref], [Google Scholar], [Publisher]
[38] M. Irani, T. Mohammadi, S. Mohebbi, Photocatalytic degradation of methylene blue with ZnO nanoparticles; a joint experimental and theoretical study, Journal of the Mexican Chemical Society, 2016, 60, 218-225. [Google Scholar], [Publisher]
[39] M. Elango, D. Nataraj, K.P. Nazeer, M. Thamilselvan, Synthesis and characterization of nickel doped cadmium sulfide (CdS: Ni2+) nanoparticles, Materials Research Bulletin, 2012, 47, 1533-1538. [Crossref], [Google Scholar], [Publisher]
[40] S.L. Wong, M.H. Mohamed Noor, N. Ngadi, I. Mohammed Inuwa, R. Mat, N.A. Saidina Amin, Aspirin adsorption onto activated carbon derived from spent tea leaves: statistical optimization and regeneration study, International Journal of Environmental Research, 2021, 15, 413-426. [Crossref], [Google Scholar], [Publisher]