TY - JOUR ID - 80609 TI - Reviewing of metalloporphyrins as novel catalysts for synthesis of conducting and water-soluble polymers JO - Advanced Journal of Chemistry, Section A JA - AJCA LA - en SN - 2645-7768 AU - Zamiraei, Zahra AU - Golzar, Maryam AU - Hamidi, Hoda AD - Environmental Research Institute, Academic Center for Education, Culture & Research (ACECR), 4144635699, Rasht, Iran AD - Department of chemistry, university campus2, university of Guilan, Rasht,Iran AD - Department of Chemistry, Payame Noor University (PNU), P. O. Box, 19395-3697 Tehran, Iran Y1 - 2018 PY - 2018 VL - 1 IS - 2 SP - 105 EP - 116 KW - Matelloporphyrin KW - Conducting Polymer KW - Water-soluble polymer KW - Oxidative polymerization DO - 10.29088/sami/AJCA.2018.1.105116 N2 - Porphyrins are a group of heterocyclic macrocycle organic compounds, composed of four modified pyrrole subunits interconnected at their α carbon atoms via methine bridges (=CH−). Porphyrins have attracted much attention because of their unique structures and a wide spectrum of very useful physicochemical and biological properties, such as anion binding, stabilization of metal ions with unusual oxidation states, electron transfer, and construction of peculiar supramolecular assemblies. The synthesis of electroactive and water-soluble polymers were accomplished with water-soluble metal(III) porphyrins in the presence of a template. The polymerization by matelloporphyrin is simple (one-step), chemically mild, and environmentally benign and requires minimal separation. This approach provides a distinct advantage over similar reactions employing native enzymes due to higher stability and lower price of the catalysts. UR - http://www.ajchem-a.com/article_80609.html L1 - http://www.ajchem-a.com/article_80609_524a511eaf936e07948479e44abe8db8.pdf ER -