Cyclic Voltammetry of Aqueous CoCl2 in the Presence of Ceftriaxone Disodium Salt (Cefs) at 298.65 K

Gomaa, Esam Arafa; Abdel Hady, MH; Mahmoud, MH; El Kot, Doaa Ahmed

doi:10.29088/sami/AJCA.2019.2.113

Document Type : Original Research Article

Authors

¹ Chemistry Department, Faculty of Science , Mansoura University, 35516 Mansoura, Egypt

² Chemistry Department,Faculty of Science, Mansoura University, Mansoura, Egypt

³ Basic Science Department,Faculty of Engineering,Masnoura University.

10.29088/sami/AJCA.2019.2.113

Abstract

Cyclic Voltammetry of Cobalt chloride with different concentrations was measured experimentally using DY2000 potentiostat. We used 0.1 M KCl as supporting electrolyte. Glassy carbon working electrode was used, purified and polished before use. The other two electrodes are platinum wire and Ag/AgCl electrode put in saturated KCl solution were used. The complex characters for the interaction of CoCl₂ with Ceftriaxone disodium salt (Cefs) were studied with the use of different Ceftriaxone disodium salt (Cefs) concentrations at 298.65 K. The oxidation, reduction mechanisms and the stability constants of the complexes formed are discussed. Scan rate and different kinetic parameters resulted from the interaction of CoCl₂ with Ceftriaxone disodium salt (Cefs) were also evaluated and their values were discussed.

Graphical Abstract

Keywords

Main Subjects

Physical chemistry

References

[1]. C.M.A. Brett, A.M.O. Brett, Electrochemistry, Oxford University Press, Oxford, 1993, Chapter 9.

[2]. E. Gileadi, Electrode kinetics for chemists, chemical Engineers and Materials Scientists, VCH, Weinheim, 1993, Chapter 25.

[3]. A.S.A. Khan, R. Ahmed, M.L. Mirza, J. Radioanal. Nucl. Chem., 2010, 283, 527-531.

[4]. D.C. Harris, Quantitative chemical analysis, seventhed., W.H. Freeman and company, New York, 2006.

[5]. W. Ong, A.E. Kaifer, J. Am. Chem. Soc., 2002, 124, 9358-9359.

[6]. H. Masuda, Y.Z. Ayabe, Electrochem., 1955, 59, 494-503.

[7]. David K. Gosser, Jr., Cyclic voltammetry : simulation and analysis of reaction mechanisms , New York (N.Y.) : VCH, 1993.

[8]. C.H. Bamford , R.G. Compton , Electrode Kinetics: Principles and Methodology, Vol. 26, 1st Edition, Elsevier Science ,1986.

[9] Dale A. C. Brownson . Criag E. Banks, The Handbook Of Graphene Electrochemistry, Springer-Verlag London Ltd. 2014

[10]. J. Wang, Analytical Electrochemistry- 3rd ed., (1948), John Wiley & Sons, Inc. 2006.

[11]. Modeling and Simulation Solutions for Chemicals and Materials Research, Materials Studio (Version 5.0), Accelrys software Inc., San Diego, USA. Available online at: www.accelrys.com 2009.

[12]. A.M. El-Askalany, A.M. Abou El-Magd, Chem. Pharm.Bull., 1995, 43, 1791-1792.

[13]. E.A. Gomaa, R.M. Abu-Qarn, J. Mol. Liq., 2017, 232,319-324.

[14]. E.A. Gomaa, M.A. Tahoon, A. Negm, J. Mol. Liq., 2017, 241, 595-602.

[15]. E.A. Gomaa, R.R. Zaky, A. Shokr, J. Mol. Liq., 2017, 242, 913-918.

[16]. E.A. Gomaa, R.R. Zaky, A. Shokr, Chem. Data. Coll., 2017, 11-12, 67-76.

[17]. E.A. Gomaa, A. Negm, M.A. Tahoon, J. Taibah. Univer. Sci., 2017, 11, 741-748.

[18]. S.E. El-Shereafy, E.A. Gomaa, A.M. Yousif, A.S. Abou El-Yazed, Iran. J. Mater. Sci. Eng., 2017, 14, 48-57.

[19]. E.A. Gomaa, H.Abdel kader, M.A.Kabeel, A. A. Elgindy, Assiut. Univer. J. Chem., (AUJC), 2017, 46, 31-36.

[20]. R.S.Nicholson, I. Shain. Anal. Chem., 1965, 37,178 -190.

[21]. G.A. Mabbott, J. Chem. Educ., 1983, 60, 697-702.

[22]. E.A. Gomaa, R.R. Zaky, A. Shokr, Assiut. Univer. J. Chem., (AUJC), 2017, 46, 37-45.

[23]. E.A. Gomaa, R.R. Zaky, M.M. Wagieh, Assiut. Univer. J. Chem., (AUJC), 2017, 47, 46-57.

[24]. E.A. Gomaa, M.A. Tahoon, J. Mol. Liq., 2016, 214, 19-23.

[25]. E.A. Gomaa, A. Negm, M.A. Tahoon, Eur. J. Chem., 2016, 7, 341-346.

[26]. E.A. Gomaa, M.A. Tahoon, A. Shokr, Chem. Data. Coll., 2016, 3-4, 58-67.

[27]. E.A. Gomaa, M.H. Mahmoud, M.G. Mousa, E.M. El-Dahshan, J. Chem. Method., 2018, 3, 1-11.

[28]. J. Anacona, A. Rodriguez, Trans. Met. Chem., 2005, 30, 897-901. [29]. S.H. Guzar, J.I.N. Qin-han, J. Applied. Sci., 2008, 8, 2480–2485.

[30]. G. A. A. Al-Hazmi, M. S. El-Shahawi , I. M. Gabr , A. A. El-Asmy, J. Coord. Chem., 2005, 58, 713-733.

[31]. K. K. Narang, V.P. Singh, Trans. Met. Chem., 1996, 21, 507–511.

[32]. A. Fekri, R. Zaky, Spectrochimi. Acta Part A., 2014, 132, 846–853.

[33]. R.H. Lee, E. Griswold, J. Kleinberg, Inorg. Chem., 1964, 3, 1278-1283.

Advanced Journal of Chemistry, Section A

Cyclic Voltammetry of Aqueous CoCl2 in the Presence of Ceftriaxone Disodium Salt (Cefs) at 298.65 K

References

References

Volume 2, Issue 1
January 2019
Pages 1-13

Cyclic Voltammetry of Aqueous CoCl2 in the Presence of Ceftriaxone Disodium Salt (Cefs) at 298.65 K

References

References

Volume 2, Issue 1January 2019Pages 1-13

Volume 2, Issue 1
January 2019
Pages 1-13