Kinetics and Mechanism of Propane-1,3-diol Oxidation by Mn(VII) in Aqueous Medium

Latona, Dayo Felix

doi:10.33945/SAMI/AJCA.2019.2.225233

Document Type : Original Research Article

Author

Dayo Felix Latona

Department of Pure and Applied Chemistry, Osun State University, PMB 4494 Osogbo, Nigeria.

10.33945/SAMI/AJCA.2019.2.225233

Abstract

The oxidation of propane-1,3-diol by potassium permanganate in aqueous solution was investigated at λmax 525 nm. The rate of the reaction was found to increase with increase in [KMnO4] and [Propane-1,3-diol]. The reaction showed first order dependence each in [KMnO4] and [Propane-1,3-diol] and independent in the ionic strength of the solution. The values of 〖∆H〗^#(kJ mol-1), 〖∆S〗^# (kJK-1mol-1) and〖 ∆G〗^#(kJ mol-1) were 24.98, -0.22 and 90.50 respectively. Negative activation of entropy revealed an ordered transition state for the reaction. Spectroscopic studies and FTIR analysis revealed the product of the reaction to be 3-hydroxy-propanone. A suitable reaction mechanism is proposed for the reaction investigated.

Graphical Abstract

Keywords

Main Subjects

Applied Chemistry

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Advanced Journal of Chemistry, Section A

Kinetics and Mechanism of Propane-1,3-diol Oxidation by Mn(VII) in Aqueous Medium

References

References

Volume 2, Issue 3 - Serial Number 184
July 2019
Pages 225-233

Kinetics and Mechanism of Propane-1,3-diol Oxidation by Mn(VII) in Aqueous Medium

References

References

Volume 2, Issue 3 - Serial Number 184July 2019Pages 225-233

Volume 2, Issue 3 - Serial Number 184
July 2019
Pages 225-233